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Radiative Heat Transfer

Definition

Transfer of heat by electromagnetic waves (infrared). Scales as the fourth power of absolute temperature; at near-flashover temperatures it can simultaneously ignite all exposed fuel surfaces.

Mechanism
Electromagnetic (infrared) energy transfer
Scaling
Proportional to absolute temperature to the 4th power
Fire relevance
Drives flashover ignition of exposed fuels

Common questions

How does radiative heat transfer differ from conduction and convection in a fire?+

Conduction and convection require direct contact or a moving fluid medium, while radiation transfers energy through electromagnetic waves across open space, which is why a hot ceiling layer can pre-heat and ignite fuel packages it never physically touches.

Why is the fourth-power temperature scaling significant for reconstructing flashover?+

Because radiative output rises so steeply with temperature, a relatively modest increase in upper-layer gas temperature can produce a large jump in radiant heat flux to the floor, which helps explain why flashover can appear to occur suddenly.

Related terms

Arrhenius Equation
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Auto-Ignition Temperature
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Carboxyhaemoglobin (COHb)
The compound formed when carbon monoxide binds to haemoglobin at the oxygen-binding site, with an affinity 200-250 times greater than oxygen. Produces...
Conductive Heat Transfer
Transfer of thermal energy through a solid material by molecular vibration. Rate depends on thermal conductivity, temperature gradient, cross-sectional area, and path...
Convective Heat Transfer
Transfer of heat by bulk movement of a fluid (gas or liquid). In compartment fires, the buoyant hot gas plume carries most...
Fire Tetrahedron
The model of sustained combustion requiring four concurrent elements: fuel, oxidiser, heat, and an uninhibited radical chain reaction. Replacing the older fire...
Flaming Combustion
Gas-phase oxidation of volatile pyrolysis products above the fuel surface, producing a visible flame at 800-1200°C. Produces less CO than smouldering under...
Flash Point
Lowest temperature at which a liquid gives off enough vapour to form an ignitable mixture in air, but the vapour does not...
Glowing (Smouldering) Combustion
Surface-phase oxidation of solid char without a gas-phase flame, typically at 400-700°C. Produces large amounts of CO and can persist at lower...

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