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Glowing (Smouldering) Combustion

Definition

Surface-phase oxidation of solid char without a gas-phase flame, typically at 400-700°C. Produces large amounts of CO and can persist at lower oxygen concentrations than flaming combustion.

Temperature range
Approximately 400 to 700C
Combustion type
Surface oxidation of solid char, no flame
Key product
Large quantities of carbon monoxide
Oxygen requirement
Lower than flaming combustion

Common questions

Why is smouldering combustion particularly dangerous in fire deaths?+

It produces large amounts of carbon monoxide while generating little visible flame or heat signature, so CO levels in an enclosed space can rise for a long period before detection, increasing the risk of poisoning before a fire is even noticed.

How can smouldering combustion transition into flaming combustion?+

If enough heat accumulates and pyrolysis gases build up, or the smouldering material is disturbed and exposed to more oxygen, the process can transition to flaming combustion, sometimes called the smoulder-to-flame transition.

How does an investigator recognise smouldering versus flaming fire damage at a scene?+

Smouldering damage tends to show deep, slow charring localised around ignition sources like a cigarette or overheated material, whereas flaming fires show faster, more extensive char and characteristic V-shaped burn patterns.

Related terms

Arrhenius Equation
Mathematical expression relating reaction rate to temperature: k = A × exp(-Ea/RT). The exponential dependence explains the self-accelerating nature of combustion as...
Auto-Ignition Temperature
The minimum temperature at which a material ignites spontaneously without a pilot flame or spark. Relevant to the assessment of ignition scenarios...
Carboxyhaemoglobin (COHb)
The compound formed when carbon monoxide binds to haemoglobin at the oxygen-binding site, with an affinity 200-250 times greater than oxygen. Produces...
Conductive Heat Transfer
Transfer of thermal energy through a solid material by molecular vibration. Rate depends on thermal conductivity, temperature gradient, cross-sectional area, and path...
Convective Heat Transfer
Transfer of heat by bulk movement of a fluid (gas or liquid). In compartment fires, the buoyant hot gas plume carries most...
Fire Tetrahedron
The model of sustained combustion requiring four concurrent elements: fuel, oxidiser, heat, and an uninhibited radical chain reaction. Replacing the older fire...
Flaming Combustion
Gas-phase oxidation of volatile pyrolysis products above the fuel surface, producing a visible flame at 800-1200°C. Produces less CO than smouldering under...
Flash Point
Lowest temperature at which a liquid gives off enough vapour to form an ignitable mixture in air, but the vapour does not...
Radiative Heat Transfer
Transfer of heat by electromagnetic waves (infrared). Scales as the fourth power of absolute temperature; at near-flashover temperatures it can simultaneously ignite...

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