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Auto-Ignition Temperature

Definition

The minimum temperature at which a material ignites spontaneously without a pilot flame or spark. Relevant to the assessment of ignition scenarios in electrical and hot-surface fire causation.

Definition
Minimum temperature for spontaneous ignition
No ignition source needed
Unlike flash point
Relevant to
Electrical and hot-surface fire causation

Common questions

How does auto-ignition temperature differ from flash point?+

Flash point is the lowest temperature at which vapors will ignite when exposed to an external spark or flame. Auto-ignition temperature is higher and needs no external ignition source at all, the material ignites on its own.

Why does auto-ignition temperature matter when investigating an electrical fire?+

It helps assess whether a hot surface alone, such as an overloaded conductor or a failed component, could plausibly have ignited nearby combustible material without any separate spark or open flame.

Related terms

Arrhenius Equation
Mathematical expression relating reaction rate to temperature: k = A × exp(-Ea/RT). The exponential dependence explains the self-accelerating nature of combustion as...
Carboxyhaemoglobin (COHb)
The compound formed when carbon monoxide binds to haemoglobin at the oxygen-binding site, with an affinity 200-250 times greater than oxygen. Produces...
Conductive Heat Transfer
Transfer of thermal energy through a solid material by molecular vibration. Rate depends on thermal conductivity, temperature gradient, cross-sectional area, and path...
Convective Heat Transfer
Transfer of heat by bulk movement of a fluid (gas or liquid). In compartment fires, the buoyant hot gas plume carries most...
Fire Tetrahedron
The model of sustained combustion requiring four concurrent elements: fuel, oxidiser, heat, and an uninhibited radical chain reaction. Replacing the older fire...
Flaming Combustion
Gas-phase oxidation of volatile pyrolysis products above the fuel surface, producing a visible flame at 800-1200°C. Produces less CO than smouldering under...
Flash Point
Lowest temperature at which a liquid gives off enough vapour to form an ignitable mixture in air, but the vapour does not...
Glowing (Smouldering) Combustion
Surface-phase oxidation of solid char without a gas-phase flame, typically at 400-700°C. Produces large amounts of CO and can persist at lower...
Radiative Heat Transfer
Transfer of heat by electromagnetic waves (infrared). Scales as the fourth power of absolute temperature; at near-flashover temperatures it can simultaneously ignite...

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