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Fluorescent Whitening Agent (FWA)

Definition

An optical brightener added to synthetic fibres and paper during manufacture; fluoresces under UV-A excitation, making treated fibres and paper highly visible under ALS.

Also called
Optical brightener
Applied to
Synthetic fibres and paper during manufacture
Excitation
UV-A
Forensic use
Increases visibility of treated fibres and paper under ALS

Common questions

How does FWA presence or absence help discriminate between fibre or paper samples in a comparison?+

Manufacturers vary in whether and how much optical brightener they add, so two visually similar fibres or papers can show markedly different fluorescence intensity or hue under UV-A. This gives an additional discriminating characteristic beyond colour and morphology when comparing questioned and known samples.

Why is FWA fluorescence useful specifically on paper documents rather than only textiles?+

Different paper stocks and production batches use different brightener formulations or concentrations, so alternate light examination can reveal inconsistencies, such as an inserted page fluorescing differently from the rest of a document, that are invisible under normal or even UV-reflected light alone.

Does the absence of FWA fluorescence mean a fibre or paper sample is unusual or suspicious?+

Not on its own. Many natural fibres and some papers are manufactured without optical brighteners at all, so a non-fluorescing sample is simply consistent with that manufacturing choice; the observation only becomes meaningful when comparing a questioned item against a specific known source.

Related terms

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Crime-Lite
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DFO (1,8-Diazafluoren-9-One)
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Long-Pass (Viewing) Filter
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Mercury Vapour Lamp
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Polilight
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Rhodamine 6G
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Stokes Shift
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Tungsten-Halogen Lamp
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Xenon Arc Lamp
A high-pressure xenon discharge lamp producing near-continuous white-light emission across 200-2500 nm; used in broadband ALS platforms (Polilight, CrimeScope) with bandpass filters.

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