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TIMS (Thermal Ionisation Mass Spectrometry)

Definition

An instrument that ionises a sample deposited on a metal filament and measures ion beam intensities with Faraday collectors. The gold standard for high-precision radiogenic isotope ratios such as Rb-Sr and U-Pb.

Ionisation method
Sample on a heated metal filament
Detector
Faraday collectors measuring ion beam intensity
Best for
High-precision radiogenic isotope ratios
Example systems
Rb-Sr and U-Pb isotope ratios

Common questions

Why is TIMS still the reference method despite newer techniques like MC-ICP-MS?+

TIMS produces very stable, low-background ion beams from a solid sample loaded on a filament, giving it exceptional precision for certain isotope systems that remains a benchmark against which faster plasma-source methods are validated.

What does TIMS contribute to a forensic provenance case?+

Radiogenic isotope ratios from TIMS can be matched against geological reference databases to narrow down the geographic region a mineral, metal or other inorganic material originated from, supporting questions of source and trafficking route.

Related terms

Delta Notation (δ)
A notation expressing the isotope ratio of a sample relative to an international standard in parts per thousand (per mil, ‰). Positive...
Epsilon Notation (ε)
Similar to delta but expressed in parts per ten thousand, used for radiogenic systems where variation is very small. Epsilon Nd and...
MC-ICP-MS (Multi-Collector Inductively Coupled Plasma Mass Spectrometry)
An instrument that ionises a liquid or laser-ablated sample in an argon plasma at about 8,000 K and simultaneously collects multiple ion...
Radiogenic Isotope
An isotope produced by radioactive decay of a parent nuclide over geological time. Its abundance in a rock or mineral increases predictably...
Stable Isotope
An isotope that does not undergo radioactive decay. Ratios of stable isotopes change only through physical or biological fractionation, such as evaporation...

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