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Phthalocyanine

Definition

Highly stable organic pigment providing intense blue (PB15, copper phthalocyanine) and green (PG7) colours; identified by Raman bands at 680 and 748 cm-1.

Colours produced
Intense blue (PB15) and green (PG7)
Blue variant
Copper phthalocyanine
Raman bands
680 and 748 cm-1
Stability
Highly stable organic pigment

Common questions

Why is phthalocyanine useful for matching automotive or forensic paint samples?+

Its high chemical stability means the pigment resists fading or degradation over time, so its Raman signature stays consistent between a questioned paint chip and a reference sample even after years of environmental exposure.

Why is Raman spectroscopy preferred over visual colour comparison for identifying this pigment?+

Different pigments and pigment blends can look visually identical under normal light, but phthalocyanine's characteristic Raman bands at 680 and 748 cm-1 give a specific, non-destructive chemical fingerprint that distinguishes it from other blue or green colourants that may look the same to the eye.

Related terms

Alkyd Resin
A polyester binder modified with fatty-acid chains from drying oils; cures by oxidative crosslinking and is characterised by FTIR ester carbonyl absorption...
Basecoat
The colour-bearing layer in automotive OEM paint; thin (10-30 µm), thermoplastic acrylic binder, contains colour and effect pigments.
Binder
The polymer matrix that holds pigments in place and bonds the paint to the substrate. Identifies paint type (alkyd, acrylic, polyurethane, epoxy)...
Clearcoat
The transparent outermost layer of automotive OEM paint; thermoset acrylic-melamine, 40-60 µm, provides UV resistance and gloss.
Effect Pigment
Aluminium flake or TiO2-coated mica used in metallic and pearlescent automotive finishes; identified by SEM morphology and EDS elemental composition.
Electrocoat (E-Coat)
The first layer in automotive OEM paint, applied by cathodic electrodeposition of an epoxy-amine coating onto the bare steel shell; 15-25 micrometres...
ENFSI EPG
Expert Working Group on Paint (European Network of Forensic Science Institutes); produced the European paint-examination protocol and promoted EUCAP development.
PDQ
Paint Data Query database (RCMP-maintained). Cross-referenced from glass work when a vehicle is identified through paired glass and paint evidence.
Refinish Paint
Paint applied in body-shop repair; typically 2K polyurethane, chemically distinct from OEM acrylic-melamine; adds extra layers visible in cross-section.
SWGMAT
Scientific Working Group for Materials Analysis, a US forensic science standards body (now succeeded by the OSAC Explosives Subcommittee). Published the Forensic...
TiO2 Polymorph
Titanium dioxide exists as rutile (Raman 143, 447, 612 cm-1) or anatase (Raman 144, 197, 399, 513 cm-1); the polymorph distinguishes premium...

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