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Light Petroleum Distillate (LPD)

Definition

The ASTM E1618 ignitable liquid class covering C4-C9 aliphatic products (charcoal lighter fluid, camping fuel, some paint thinners). The class most frequently subject to false-positive identification due to overlap with polyethylene pyrolysis products.

Standard
ASTM E1618 ignitable liquid class
Carbon range
C4 to C9 aliphatic
Examples
Charcoal lighter fluid, camping fuel, some paint thinners
Key risk
False positives from polyethylene pyrolysis products

Common questions

Why is the LPD class especially prone to false-positive identification?+

When common plastics like polyethylene burn, their pyrolysis breaks down into aliphatic hydrocarbons that fall in a similar carbon range and chromatographic pattern to genuine light petroleum distillates, so an analyst can mistake melted plastic residue for an ignitable liquid unless the full pattern is carefully evaluated.

How do analysts guard against mistaking pyrolysis products for LPD?+

ASTM E1618 interpretation relies on evaluating the complete chromatographic pattern, including the relative distribution of compounds and diagnostic ratios, rather than any single peak, since pyrolysis-derived hydrocarbons rarely reproduce the full characteristic pattern of a genuine petroleum product.

Related terms

ASTM E1618
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The standard elution solvent for activated charcoal strips in ASTM E1412 passive headspace analysis. Selected for its low UV absorption, minimal GC-FID...
Evaporative Weathering
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Extracted Ion Profile (EIP)
A GC-MS chromatographic display plotting only ions of a specified m/z value against retention time, effectively filtering out all compounds that do...
Ignitable Liquid Reference Collection (ILRC)
A database of GC-MS chromatographic data for over 1,100 ignitable liquid products maintained by the National Centre for Forensic Science at the...
Passive Headspace Concentration
The ASTM E1412 method in which an activated charcoal strip is suspended in a sealed container above heated fire debris (60-80°C, 16...
Total Ion Chromatogram (TIC)
A GC-MS chromatographic output plotting the summed intensity of all detected ions at each retention time. Provides the full-pattern overview of a...
Tropylium Cation (M/z 91)
The C7H7+ fragment ion produced by rearrangement of alkylbenzenes in the EI ion source of a mass spectrometer. The diagnostic ion for...
Unresolved Complex Mixture (UCM)
The broad hump of hundreds of co-eluting cycloalkane and isoalkane compounds in the TIC of heavy petroleum products (diesel, heavy fuel oil,...

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