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Diphenylamine (DPA) Test

Definition

A broad-spectrum presumptive colour test for nitrate and nitrite compounds, producing a blue-green coloration. Reactive with multiple oxidising agents, so environmental context is essential to interpreting a positive result.

Detects
Nitrate and nitrite compounds
Positive result
Blue-green coloration
Result type
Presumptive, not confirmatory
Field
Field explosives detection

Common questions

Why does the DPA test require environmental context to interpret?+

Many common oxidising agents besides explosive residues can trigger the colour change, so a positive result on soil, fertiliser residue, or vehicle exhaust particulate does not by itself confirm explosive material; the scene and item source have to be weighed alongside the chemistry.

What follow-up is needed after a positive DPA test?+

A confirmatory instrumental method, such as ion chromatography or mass spectrometry, is required before a nitrate or nitrite finding is reported as identified rather than merely presumptively indicated.

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