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X-ray fluorescence (XRF)

Definition

A technique in which a sample is irradiated with a primary X-ray beam, causing its constituent elements to emit characteristic secondary (fluorescent) X-rays that are measured to determine elemental composition.

Related terms

Energy-dispersive XRF (ED-XRF)
An XRF configuration using a solid-state detector that registers all emitted photon energies simultaneously. Faster and more compact than WD-XRF, enabling portable...
Fused bead
A preparation method where soil is dissolved in molten lithium tetraborate or metaborate flux at around 1100 degrees Celsius to form a...
Matrix effect
The absorption or enhancement of characteristic X-rays by other elements in the same sample, causing apparent concentrations to deviate from true values...
Pressed pellet
A sample preparation form in which finely ground, dried soil is mixed with a binder and compressed under several tonnes of pressure...
Wavelength-dispersive XRF (WD-XRF)
An XRF configuration that uses an analysing crystal to separate emitted X-rays by wavelength before detection, giving high spectral resolution and low...

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