TLC (Thin-Layer Chromatography)
Definition
A planar chromatography technique on silica gel plates that separates ink dye mixtures by polarity. ASTM E2285 governs its forensic application. The Rf values and band colours under visible and UV light constitute the ink's chromatographic fingerprint.
Related terms
- ASTM E2285 / E2286
- The two ASTM International standards governing forensic ink examination: E2285 covers TLC-based ink alteration examination; E2286 covers HPLC-based ink comparison. Both are...
- Ballpoint Ink
- An oil-based, high-viscosity ink using a resin binder (alkyd or polyamide) in a high-boiling solvent (phenoxyethanol or benzyl alcohol), with triphenylmethane dyes...
- HPLC-DAD
- High-performance liquid chromatography with diode-array detection. Separates ink dyes on a C18 column and records UV-visible spectra at each elution point, providing...
- Iron-Gall Ink
- A historical ink formulation of ferrous sulphate, tannic acid (from oak galls), and gum arabic. The ferrous-tannate complex oxidises to brown ferric-tannate...
- Phenoxyethanol
- The primary high-boiling solvent in most modern ballpoint ink formulations. Its progressive evaporation from the dried ink film after writing is the...
- Raman Microspectroscopy
- A vibrational spectroscopy technique using a focused laser beam to excite molecular vibrations in an ink sample. Non-destructive. Primary method for toner...
- Toner
- A dry-powder printing material consisting of fine styrene-acrylate polymer particles carrying carbon black and organic pigment, electrostatically applied and thermally fused at...
- USSS International Ink Library
- A collection of ~10,000 dated writing ink formulations maintained by the United States Secret Service since 1968, providing a terminus post quem...
- VSC (Video Spectral Comparator)
- A multispectral imaging instrument used in document examination; illuminates the document at multiple wavelengths (UV, visible, near-IR, IR) and captures fluorescence and...
Explained in
- Ink Chemistry: TLC, HPLC, Raman and the Video Spectral Comparator WorkflowA planar chromatography technique on silica gel plates that separates ink dye mixtures by polarity. ASTM E2285 governs its forensic application. The Rf values...