Planck-Einstein Equation
Definition
E = hν = hc/λ; relates photon energy to frequency and wavelength. Foundation of all spectral energy calculations.
- Formula
- E = hν = hc/λ
- Relates
- Photon energy to frequency and wavelength
- Constant
- Planck's constant, h
- Application
- Foundation of spectral energy calculations
Common questions
Why does this equation matter for choosing a forensic light source?+
It shows that shorter-wavelength light carries higher photon energy, which is why UV and blue-light sources are chosen to excite fluorescence in evidence such as biological fluids or altered documents, while longer-wavelength light is used for penetration or contrast in other examinations.
How does the equation connect to interpreting an absorption or emission spectrum?+
Each peak in a spectrum corresponds to a specific photon energy, and converting between wavelength, frequency, and energy using this relationship lets an examiner match an observed peak to the electronic or vibrational transition of a known substance.
Related terms
- Chromophore
- The molecular subunit responsible for a dye's colour, typically a conjugated double-bond system; chemical erasure destroys the chromophore while leaving the decolourised...
- Ionising Radiation
- Electromagnetic radiation whose photon energy exceeds the ionisation potential of atoms (typically above ~10 eV); includes gamma rays and X-rays. UV below...
- Mid-Infrared (Mid-IR)
- The 2500-25000 nm (400-4000 cm^-1) spectral region where functional-group vibrational absorptions serve as chemical fingerprints; the operating region of FTIR spectroscopy.
- Photon
- A quantum of electromagnetic radiation; a discrete energy packet with energy E = hν where h is Planck's constant and ν is...
- Photon Energy (eV)
- Photon energy expressed in electron volts; UV photons carry 3-12 eV (chemically reactive), visible 1.8-3.1 eV, mid-IR 0.05-0.5 eV (vibrational excitation only).
- Refractive Index
- A physical property of glass (and other transparent materials) that describes how much light bends when passing through it. Forensic glass comparison...
- Soret Band
- The intense porphyrin absorption band of haemoglobin at 415 nm; the spectral basis for bloodstain contrast enhancement.
- UV-a
- The ultraviolet band from 315 to 400 nm; the primary band used for UV-reflectance forensic imaging of bruises, GSR, and bite marks...
- UV-C
- Ultraviolet radiation in the 100-280 nm band; the 254 nm germicidal line excites biological-fluid fluorescence in forensic screening.
- Wave-Particle Duality
- The quantum-mechanical property of electromagnetic radiation: it behaves as a wave (diffraction, interference, polarisation) and as a stream of photons (photoelectric effect,...
- Wavenumber (Cm^-1)
- Reciprocal of wavelength in centimetres, the standard unit for mid-infrared spectra; 1 cm^-1 = 10^7 / λ(nm).