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Photodegradation

Definition

Breakdown of biological molecules driven by ultraviolet and visible radiation. In bloodstains it accelerates haemoglobin oxidation and cleaves DNA strands, hastening ageing of both colour and DNA yield.

Related terms

Haemichrome
A further oxidation product formed when the globin chains of methaemoglobin denature and the haem group becomes internally coordinated. Associated with the...
Methaemoglobin
An oxidised form of haemoglobin in which ferrous iron (Fe2+) is converted to ferric iron (Fe3+), unable to carry oxygen. Its formation...
Oxyhaemoglobin
The form of haemoglobin in freshly shed arterial blood, where iron in the haem group is in the ferrous (Fe²⁺) state and...
Protein denaturation
Unfolding and cross-linking of protein structure under heat, desiccation, or chemical stress. Affects haemoglobin, albumin, and other blood proteins as a stain...
Substrate effect
The influence of the surface on which a bloodstain lies on the rate and character of chemical change. Porous substrates absorb blood...

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