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Phenolic Resin

Definition

A class of synthetic polymer binder formed by condensation of phenols with formaldehyde; used in ballpoint ink vehicles since the 1950s; identifiable by FTIR carbonyl absorption at 1700-1720 cm-1.

Chemistry
Phenol-formaldehyde condensation polymer
Use
Binder in ballpoint ink vehicles since the 1950s
Detection
FTIR carbonyl absorption at 1700-1720 cm-1
Polymer class
Thermosetting synthetic resin

Common questions

Why does an ink examiner care about the resin, not just the dye?+

The resin binder controls how the ink flows, dries, and ages on paper, so its FTIR signature can help place an ink formulation within a manufacturing era or narrow down a brand, independent of the colorant used.

Can phenolic resin alone date a document?+

No; its presence only confirms a ballpoint ink consistent with post-1950s manufacture. Dating a specific writing to a date range needs solvent-loss or other comparative methods layered on top.

How is the FTIR carbonyl peak used practically in casework?+

An examiner compares the carbonyl absorption position and shape of a questioned ink against a reference library or a known-source ink, since resin formulation differences shift the peak and help discriminate between similar-looking inks.

Related terms

BKA Ink Reference Collection
The Bundeskriminalamt (German Federal Criminal Police Office) reference database of European pen ink formulations, used as the evidentiary baseline for questioned-document cases...
Carbon Black
A colloidal carbon pigment produced by incomplete combustion; the primary colourant in permanent black gel inks, Indian inks, and archival drawing inks;...
Ink Tagging Programme
A voluntary scheme begun in 1979 whereby participating pen manufacturers add annual chemical tags (rare-earth chelates or fluorescent markers) to their formulations;...
Iron-Gall Ink
A historical ink formulation of ferrous sulphate, tannic acid (from oak galls), and gum arabic. The ferrous-tannate complex oxidises to brown ferric-tannate...
Manufacturing Change Window
The interval between when an ink formulation was introduced and when it was discontinued or reformulated; documents with ink outside this window...
Phenoxyethanol (2-Phenoxyethanol)
A semi-volatile high-boiling solvent that constitutes a major component of ballpoint ink vehicles; its gradual loss from the dried ink film after...
Shear-Thinning (Pseudoplastic)
A rheological property where viscosity decreases under applied shear force; the gel ink delivery mechanism depends on this property: the gel liquefies...
Triarylmethane Dye
A class of synthetic dyes (including crystal violet, Victoria blue B) that form the primary colourant in most blue ballpoint inks; characterised...
USSS International Ink Library
A collection of ~10,000 dated writing ink formulations maintained by the United States Secret Service since 1968, providing a terminus post quem...

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