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Hot Corrosion

Definition

Accelerated degradation of a superalloy or coated turbine component by molten sulfate or vanadate deposits that flux and dissolve the protective oxide scale, allowing continued rapid attack.

Affected components
Superalloy or coated turbine parts
Agents
Molten sulfate or vanadate deposits
Mechanism
Flux dissolves protective oxide scale
Result
Accelerated, continued material attack

Common questions

How does hot corrosion differ from ordinary high-temperature oxidation?+

Ordinary oxidation forms a stable protective scale that slows further attack, while hot corrosion involves molten salt deposits that actively dissolve or flux that scale away, exposing fresh metal to continued rapid degradation rather than self-limiting protection.

What contaminants commonly trigger hot corrosion in turbine failure investigations?+

Sulfur from fuel combustion combined with sodium or vanadium, often introduced through contaminated fuel, sea-salt-laden intake air in marine environments, or ash-forming impurities, are common sources investigators look for when hot corrosion is suspected.

Related terms

Creep
Time-dependent plastic deformation of a material under sustained stress at elevated temperature, occurring at stress levels below the conventional yield strength.
Grain-Boundary Sliding
Relative motion of adjacent grains along their shared boundary, a key deformation mechanism at elevated temperature that opens voids at triple points...
Larson-Miller Parameter (LMP)
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Minimum Creep Rate
The steady-state strain rate during secondary creep, the single most important material parameter for structural life assessment under creep conditions.
Reheat Cracking
Intergranular cracking in the heat-affected zone of welds in certain alloy steels during post-weld heat treatment or early elevated-temperature service, caused by...

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