CVAAS
Definition
Cold-vapour AAS. Mercuric ions are reduced by stannous chloride or sodium borohydride to elemental mercury vapour, swept by argon into a quartz absorption cell at 253.7 nm. The standard mercury method.
Related terms
- AAS
- Atomic absorption spectrometry. Free ground-state atoms in a vapour absorb a characteristic resonance wavelength from a hollow-cathode lamp, and Beer-Lambert converts the...
- Background Correction
- A method (deuterium continuum, Zeeman effect, Smith-Hieftje self-reversal, or high-resolution continuum-source) that subtracts non-atomic absorption (molecular bands, scatter) from the raw absorbance...
- GFAAS
- Graphite-furnace AAS, also called electrothermal AAS. A graphite tube heated electrically through a programmed ramp atomises a microlitre aliquot, giving roughly 100...
- HG-AAS
- Hydride-generation AAS for hydride-forming elements (As, Sb, Se, Bi, Te, Sn, Ge). Sodium borohydride in acid generates the volatile hydride, which is...
- Hollow Cathode Lamp (HCL)
- A sealed lamp whose cathode is made of the element being analysed, filled with argon or neon at low pressure. Strikes a...
Explained in
- Atomic Absorption Spectrometry: Flame, Graphite Furnace, Cold VapourCold-vapour AAS. Mercuric ions are reduced by stannous chloride or sodium borohydride to elemental mercury vapour, swept by argon into a quartz absorption cell...