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Bromoform

Definition

CHBr3, density 2.89 g/cm3; the denser component of the forensic density-gradient liquid mixture, used to create the bottom of the density range.

Formula
CHBr3
Density
2.89 g/cm3
Role
Denser component of density-gradient liquid mixture
Application
Forensic soil and mineral density gradient

Common questions

What does bromoform's high density let it separate in soil examination?+

At the bottom of the density range it separates the densest minerals, such as certain heavy accessory minerals, from lighter quartz and organic material, which helps characterise a soil sample's mineral composition for comparison purposes.

Why must bromoform concentration be controlled precisely in a gradient column?+

Because the column's separating power depends on a smooth, accurately known density gradient, small errors in the bromoform-to-bromobenzene ratio shift where particles settle, which can misrepresent the true density distribution of the sample being examined.

Related terms

Bromobenzene
C6H5Br, density 1.50 g/cm3; the lighter component of the forensic density-gradient liquid mixture.
D-Spacing
The perpendicular distance between adjacent parallel planes of atoms in a crystal lattice, measured in angstroms or nanometres. Each set of planes...
Density-Gradient Column
Glass column filled with stepwise layers of liquids of decreasing density (commonly bromoform 2.89 g/cm3 and bromobenzene 1.50 g/cm3 mixed in known...
Diatom Frustule
The siliceous cell wall of a diatom, composed of biogenic opal; species-specific in shape and ornament, and resistant to degradation in soil...
Forensic Palynology
The application of pollen and spore analysis to legal investigations. A forensic palynologist identifies the species composition of pollen assemblages from crime-scene...
Heavy-Mineral Fraction
The sub-fraction of soil mineral grains with density above 2.85 g/cm3, including pyroxene, hornblende, garnet, zircon, rutile, and tourmaline; particularly diagnostic of...
Indicator Species (Pollen)
Pollen taxa with restricted geographic ranges or specific habitat requirements, contrasted with background species that occur everywhere; indicator species provide site-specific geographic...
Laser Diffraction (PSD)
A particle-size analysis technique that measures the angular distribution of laser light scattered by suspended particles to produce a continuous grain-size distribution...
Murray-Tedrow Framework
The tiered forensic-soil comparison protocol established by Raymond Murray and John Tedrow in their 1992 text 'Forensic Geology,' which organises soil examination...
Powder XRD
X-ray diffraction analysis of a finely ground mineral sample, producing a diffractogram with peaks at positions (2θ angles) diagnostic of crystalline mineral...
Sporopollenin
The highly chemically inert polymer forming the outer wall (exine) of pollen grains and spores. Resistant to acid, alkali, oxidation, and biological...

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