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Alite (C3S)

Definition

Tricalcium silicate, 3CaO.SiO2. Dominant clinker phase (50 to 70 percent). Hydrates fast, gives early strength up to 28 days.

Chemical name
Tricalcium silicate
Formula
3CaO.SiO2
Clinker share
50 to 70 percent
Hydration speed
Fast
Strength contribution
Early strength up to 28 days

Common questions

Why does the proportion of alite in a clinker matter forensically?+

The relative proportions of clinker phases like alite reflect the specific cement formulation and manufacturing process used, so comparing phase composition between a questioned concrete sample and a reference source can support or exclude a common origin.

How does alite's role differ from the other main clinker phase, belite?+

Alite hydrates quickly and drives early strength gain within the first month, while belite hydrates more slowly and contributes strength over a longer term, so the ratio between the two phases affects how a concrete's strength develops over time.

Related terms

Aluminate (C3A)
Tricalcium aluminate, 5 to 10 percent. Reacts violently with water, attacked by sulphate. SRC cement is low in C3A.
Belite (C2S)
Dicalcium silicate, 2CaO.SiO2. 15 to 30 percent. Hydrates slow, gives long-term strength beyond 28 days.
C-S-H Gel
Calcium silicate hydrate, the main hydration binder. Amorphous, broad hump on XRD.
Clinker
The nodular intermediate product of Portland-cement manufacture, consisting of C3S, C2S, C3A and C4AF mineral phases before grinding.
Ettringite
A calcium sulfoaluminate hydrate that forms early in cement hydration and can re-form later from delayed sulfate attack; its presence or alteration...
Portland Cement
A hydraulic binder produced by firing calcium and silica sources at 1450°C; the four clinker phases (C3S, C2S, C3A, C4AF) hydrate on...
Portlandite
Calcium hydroxide (Ca(OH)2) crystallised during cement hydration; a bright birefringent phase visible in thin section that dissolves progressively as concrete carbonates, providing...

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