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Denaturation

Definition

The separation of double-stranded DNA into two single strands by disrupting the hydrogen bonds between base pairs. In PCR, denaturation is achieved by heating to approximately 94-95 degrees Celsius. G-C-rich sequences require higher temperatures to denature than A-T-rich sequences because each G-C pair has three hydrogen bonds versus two for A-T.

Related terms

Antiparallel Orientation
The two strands of the DNA double helix run in opposite directions: one strand reads 5' to 3', its complement reads 3'...
A-Addition
The non-templated addition of a single adenine nucleotide to the 3' end of PCR products by Taq polymerase, exploited in forensic STR...
AmpliTaq Gold
A chemically modified hot-start form of Taq polymerase (Applied Biosystems) that is inactive at room temperature and requires a 10-11 minute activation...
Annealing Temperature
The reduced temperature (50-65°C) at which primers hybridise to single-stranded template. Determined by primer Tm; set to balance specificity against yield.
Base Complementarity
The specific pairing rules that govern double-stranded DNA: adenine pairs with thymine (2 hydrogen bonds) and guanine pairs with cytosine (3 hydrogen...
Base Pair (Bp)
A complementary pairing of nitrogenous bases on opposite strands of double-stranded DNA: adenine with thymine (two hydrogen bonds) or guanine with cytosine...
Complementarity
The property by which each base pairs with only one specific partner (A with T, G with C). Complementarity allows a single...
Deoxyribonucleotide
The monomer unit of DNA, consisting of a deoxyribose sugar, a phosphate group, and one of four nitrogenous bases (adenine, thymine, guanine,...
Extension
The PCR step at ~72°C at which thermostable DNA polymerase synthesises a new complementary strand from each primer, using dNTPs in the...
GC Content
The proportion of base pairs in a DNA molecule that are guanine-cytosine. Because G-C pairs form three hydrogen bonds (versus two for...
Hot-Start Polymerase
Any Taq formulation (antibody-mediated, chemically modified, or aptamer-blocked) that is inactive below ~60°C, preventing non-specific amplification during reaction setup.
Melting Temperature (Tm)
The temperature at which half of a primer-template duplex population is dissociated. Depends on primer length, GC content, and nearest-neighbour stacking interactions.

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