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Photoionisation Detector (PID)

Definition

An electronic instrument that uses a UV lamp (typically 10.6 eV) to ionise organic vapour molecules and measures the resulting ion current. Detects aromatic and aliphatic hydrocarbons at ppb to ppm concentrations.

Detection principle
UV lamp ionises vapour molecules, ion current measured
Lamp energy
Typically 10.6 eV
Sensitivity range
Parts per billion to parts per million
Target compounds
Aromatic and aliphatic hydrocarbons

Common questions

How does a PID differ from a canine in accelerant screening?+

A PID gives a numeric, instrument-based reading that can be logged and repeated, while a canine gives a trained behavioural alert. Investigators often use the canine to narrow the search area quickly, then confirm and document specific spots with the PID before sampling.

Can a PID identify which accelerant is present?+

No. A PID only signals that ionisable vapour is present above background level, it does not distinguish gasoline from other hydrocarbon sources. Confirmation and identification require laboratory analysis of a collected sample, typically by gas chromatography.

Related terms

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Comparison Sample
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Handler Cueing
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NFPA 921
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SWGFEX
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Vapour Loss
The escape of low-boiling hydrocarbon fractions from a sealed fire debris sample through an imperfect container seal, or by volatilisation during warm...

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