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Haemochromogen

Definition

A reduced haem-nitrogenous-base complex. In the Takayama test, pyridine is the base, giving pyridine haemochromogen: pink, feathery or needle-like crystals.

Definition
Reduced haem-nitrogenous-base complex
Takayama base
Pyridine
Product name
Pyridine haemochromogen
Crystal appearance
Pink, feathery or needle-like crystals

Common questions

How does the Takayama test's haemochromogen differ from the Teichmann test's haemin?+

Both tests form a haem-based crystal used to confirm blood, but Teichmann produces an oxidised chlorohemin crystal using a halide salt, while Takayama produces a reduced pyridine haemochromogen crystal using pyridine and a reducing sugar, giving the two tests different crystal shapes and colours to examine microscopically.

Why is a reducing agent needed to form pyridine haemochromogen?+

The haem iron must be in a reduced state to bind pyridine and form the haemochromogen complex, so the Takayama reagent includes a reducing sugar such as glucose alongside pyridine and sodium hydroxide to drive the haem into the correct oxidation state for crystal formation.

Related terms

Confirmatory Test
A test with sufficient specificity to establish the identity of a biological fluid for reporting purposes. Examples include Takayama and Teichmann crystal...
Glacial Acetic Acid
Concentrated acetic acid (near 100%), used in the Teichmann reagent to provide an acidic medium that helps oxidise haem and incorporate the...
Haemin (Chlorohemin)
The oxidised, halide-salt form of haem produced in the Teichmann test. Haemin crystals are brown, rhomboid, and form in pairs or groups...
Pyridine
An aromatic nitrogen heterocycle used as a secondary denaturant in Indian denatured spirit formulations (at 1-2% v/v). Its presence in a headspace...
Sensitivity Limit
The minimum amount of blood (or age/dilution of stain) at which the crystal test can still produce identifiable crystals. Below this threshold...

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