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Calcium Silicate Hydrate (C-S-H)

Definition

The principal binding phase produced when Portland cement reacts with water; a gel-like material that gives concrete most of its strength and whose texture under the microscope reflects the water-to-cement ratio and curing history.

Role
Principal binding phase in hydrated Portland cement
Structure
Gel-like, amorphous
Reflects
Water-to-cement ratio and curing history
Contribution
Primary source of concrete strength

Common questions

How does examining C-S-H texture help in a structural failure investigation?+

Under microscopy the density and porosity of the C-S-H gel can indicate whether a mix was cured properly or used an excessive water-to-cement ratio, both of which weaken concrete, giving investigators physical evidence relevant to a construction defect or collapse case.

Is C-S-H the same substance in every concrete sample regardless of mix design?+

No. Its exact composition and morphology vary with the cement chemistry, water content, admixtures and curing conditions used, which is why its microstructure can be diagnostic when comparing a failed sample against specification requirements.

Related terms

Aggregate
The granular filler (sand, gravel, crushed rock) that occupies 60-80% of a concrete volume; its mineralogy, grain shape, and size distribution are...
Carbonation Front
The boundary in concrete where atmospheric CO2 has converted portlandite to calcite; the depth of this front (measured in millimetres) is used...
Ettringite
A calcium sulfoaluminate hydrate that forms early in cement hydration and can re-form later from delayed sulfate attack; its presence or alteration...
Petrographic Thin Section
A slice of material ground to 30 micrometres and mounted on a glass slide for transmitted polarised light microscopy; the standard tool...
Portlandite
Calcium hydroxide (Ca(OH)2) crystallised during cement hydration; a bright birefringent phase visible in thin section that dissolves progressively as concrete carbonates, providing...

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